Electromeric Effect
*Introduction
to Electromeric Effect*
- The *Electromeric Effect* is a temporary effect
that occurs in organic compounds when an attacking reagent interacts with the
molecule. It leads to the *complete
transfer of a pair of π electrons* from one atom to another in the
molecule.
- This effect is significant in the presence of multiple bonds (such as C=C or C=O), and is reversed once the attacking reagent is removed.
Negative Inductive
Effect (-I Effect):
- When an *electron-withdrawing group (EWG)* is attached to a carbon
chain, it pulls electron density away from the chain. This leads to a decrease in electron density along the chain.
- Example: ( C - C
δ+++ -- C
δ++ -- C
δ+--
A δ-)
- Here, A is an electron-withdrawing
group, causing a partial positive charge buildup on the adjacent carbons as
electron density is pulled towards A.
*-I
Effect Order:*
*Halogens:*
- F > Cl > Br > I
General Concepts of Organic
Chemistry
Organic Chemistry:
“Branch of
chemistry which deals with carbon compounds and its derivatives.”
Carbon (abundant ) → Tetravalent (4 bonds)
Organic
Reactions:
Chemical reactions that are undergone by organic
compounds .
Factors that
determine the reactivity of organic reactions:
What are Silicates? Their Types and Industrial Applications
.PNG)
What are Alums? Their preparation methods and Applications
.PNG)
Third group members of P-Block Element and their anomalous Properties
.png)
Nomenclature of Alkanes (IUPAC Rules) : The IUPAC (International Union of Pure and Applied Chemistry) system provides systematic rules ...
.png)
.png)