Stability of Alkenes
There are two factors for determining the stability of alkenes
Stability of Alkenes
There are two factors for determining the stability of alkenes
Wittig Reaction
The Wittig Reaction is a very useful method for the synthesis of alkenes. In this reaction, aldehydes and ketones react with phosphorus ylides to form alkenes.
Cope Reaction
When
tertiary amine oxides are heated to about 150°C, they undergo thermal
elimination to form alkenes. This reaction is known as the Cope
Reaction.
Pyrolytic Eliminations
Pyrolytic
elimination reactions are those in which the elimination occurs through heating
and involves a cyclic transition state. These reactions occur
without requiring the addition of external reagents like acids or bases.
Instead, the heat provides the necessary energy to facilitate the elimination.
Preparation of Alkenes
1.
Dehydrohalogenation of alkyl halides:
Alkenes can be prepared by the elimination of hydrogen halide from an alkyl halide. Hydrogen and halogen are removed from adjacent carbon atoms, resulting in the introduction of a carbon-carbon double bond in the molecule.
Alkenes
Introduction
Alkenes
are hydrocarbons that contain at least one carbon-carbon double bond. They
follow the general formula CnH2n. A
double bond makes them unsaturated and more reactive than alkanes.
Olefins is another name for alkenes, derived from "olefiant gas" (oil-forming gas). This term historically referred to ethene () because it reacts with chlorine to form an oily liquid.
Reactions of alkenes: